Bond's Skyfall was named Film of the Year, while Riseborough and Jones picked up the top acting trophies for their roles in Shadow Dancer and Berberian Sound Studio, respectively.
Jones' win was a shock to many as Daniel Day-Lewis was expected to continue his awards season dominance and pick up the Best Actor honour for his portrayal of former U.S. President Abraham Lincoln in Lincoln.
The prizegiving ceremony was held at the London Film Museum.
The list of winners is:
Film of the Year - Skyfall
Best Actor - Toby Jones (Berberian Sound Studio)
Best Actress - Andrea Riseborough (Shadow Dancer)
Best Screenplay - Malcolm Campbell (What Richard Did)
London Film Museum Award for Technical Achievement - Jacqueline Durran, Sarah Greenwood & Seamus McGarvey (Anna Karenina)
Peter Sellers Award for Comedy - Ben Wheatley (Sightseers)
Most Promising Newcomer - Sally El Hosaini (writer/director My Brother the Devil)
Best Documentary - The Imposter
Editor's Award - Sacha Baron Cohen